- PII
- 10.31857/S0132344X22600424-1
- DOI
- 10.31857/S0132344X22600424
- Publication type
- Status
- Published
- Authors
- Volume/ Edition
- Volume 49 / Issue number 6
- Pages
- 375-382
- Abstract
- Two uranyl succinate polymers, NH4[UO2(Suc)(HSuc)]∙H2O (I) and [UO2(Suc)(H2O)2] (II), where Suc = succinate ion (C4H4O2−4 ), were synthesized and studied by X-ray diffraction, IR spectroscopy, and thermography (CCDC nos. 2202634 and 2202635, respectively). The main structural units in the crystals of I are infinite zigzag chains [UO2(Suc)(HSuc)]–, corresponding to the AQ02B01 crystal chemical formula (A = UO2+2, Q02 = C4H4O2−4, B01 = C4H5O−4 ). It was established that in structure II, the electrically neutral [UO2(Suc)(H2O)2] chains correspond to the AQ02M12 crystal chemical formula (A = UO2+2, Q02 = C4H4O2−4, M1 = H2O). The intermolecular interactions in structures I and II were analyzed using the method of molecular Voronoi–Dirichlet polyhedra.
- Keywords
- комплексы уранила сукцинат-ионы кристаллическая структура полиэдры Вороного–Дирихле
- Date of publication
- 01.06.2023
- Year of publication
- 2023
- Number of purchasers
- 0
- Views
- 12
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