- PII
- 10.31857/S0132344X22600485-1
- DOI
- 10.31857/S0132344X22600485
- Publication type
- Status
- Published
- Authors
- Volume/ Edition
- Volume 49 / Issue number 8
- Pages
- 451-457
- Abstract
- The reaction of cluster complex (nBu4N)2[Mo3Se7Br6] with tetrabromocatechol (H2Tbc) in the presence of Et3N and Ph4PBr results in the formation of (Ph4P)2[Mo3Se7(Tbc)3]∙2MeOH (Ia∙2MeOH). Under the same conditions, the tungsten analogue (nBu4N)2[W3S7Br6] is completely or partly destroyed to give the complex (Ph4P)(Et3NH)[WO2(Tbc)2] (II). The structures of Ia·2MeOH and II were established by X-ray diffraction analysis (CCDC nos. 2213900 and 2213901, respectively). The redox properties of complex Ia and related (Ph4P)2[Mo3S7(Tbc)3] (Ib) and (Ph4P)2[Mo3S7(Tcc)3] (Ic) (Tcc is tetrachlorocatecholate) were also studied by cyclic voltammetry.
- Keywords
- молибден вольфрам кластеры редокс-активные лиганды циклическая вольтамперометрия
- Date of publication
- 01.08.2023
- Year of publication
- 2023
- Number of purchasers
- 0
- Views
- 14
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