- PII
- 10.31857/S0132344X22700086-1
- DOI
- 10.31857/S0132344X22700086
- Publication type
- Status
- Published
- Authors
- Volume/ Edition
- Volume 49 / Issue number 1
- Pages
- 36-43
- Abstract
- The reactions of TpReO(SnC3H7)2 (Tp = tris(pyrazolyl)borate anion) with acetonitrile complexes PdCl2(MeCN)2 and PtI2(MeCN)2 in toluene solutions resulted in the formation of new heterometallic rhenium complexes TpReO(µ-SnC3H7)2MX2 (MX2 = PdCl2 (I), MX2 = PtI2 (II)). A similar complex TpReO(µ-SnC3H7)2PdI2 (III) was formed either on treatment of I with NaI in dichloromethane or in the reaction of TpReO(SnC3H7)2 with a suspension of PdI2 in toluene. Complexes I–III were characterized by IR and NMR spectroscopy and by X-ray diffraction (CCDC nos. 2172225–2172227).
- Keywords
- комплексы рения тиолатные комплексы гетерометаллические комплексы <i>трис</i>(пиразолил)борат рентгеноструктурный анализ
- Date of publication
- 01.01.2023
- Year of publication
- 2023
- Number of purchasers
- 0
- Views
- 11
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