- PII
- 10.31857/S0132344X23700238-1
- DOI
- 10.31857/S0132344X23700238
- Publication type
- Status
- Published
- Authors
- Volume/ Edition
- Volume 49 / Issue number 6
- Pages
- 360-366
- Abstract
- The trinuclear cobalt(III) complex [(Bipy)5Co3(L)2](Cl)3 (I) is synthesized by the template reaction of 2,2'-(1H-imidazole-4,5-diyl)bis(4-ethylphenol) (L) and bis(2,2-bipyridine)cobalt(II) dichloride in the presence of diazabicycloundecene. The complex is isolated in the individual state and characterized by elemental analysis, cyclic voltammetry, UV-VIS spectroscopy, and X-ray diffraction (XRD) (CIF file СCDC no. 2201135). According to the obtained data, the cobalt ions in trinuclear complex I have the oxidation state +3, and the complex formation occurs with the oxidation of the initial cobalt(II) ions.
- Keywords
- полиядерные комплексы кобальта редокс-активные лиганды рентгеноструктурный анализ циклическая вольтамперометрия УФ-вид. спектроскопия
- Date of publication
- 01.06.2023
- Year of publication
- 2023
- Number of purchasers
- 0
- Views
- 14
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