- PII
- 10.31857/S0132344X23700330-1
- DOI
- 10.31857/S0132344X23700330
- Publication type
- Status
- Published
- Authors
- Volume/ Edition
- Volume 49 / Issue number 12
- Pages
- 772-781
- Abstract
- A number of new bimetallic acetate and pivalate complexes of the Pd–Mn system have been synthesized and structurally characterized. The starting complex [Pd(OOCMe)4Mn] reacts with N donor ligands such as 1,10-phenanthroline to form [Pd(OOCMe)4Mn(phen)]·MeCN (I) (CIF file CCDC no. 2217716). The reactions of substitution of acetate bridges for pivalate bridges in heterometallic carboxylate Pd–Mn complexes have been studied; It has been shown that complete replacement of all acetate bridges with pivalate bridges is possible both in the heterometallic complex (I), in which there is a ligand coordinated to an additional metal atom, with the formation of the compound [Pd(Piv)4Mn(phen)]·C6H6, (II) ( CIF file CCDC No. 2217717), structurally close to the original acetate complex, and in the acetate complex [Pd(OOCMe)4Mn]. The heterometallic pivalate cocrystallizate [Pd(Piv)4Mn 2HPiv] (III) obtained in the latter case (CIF file CCDC No. 2217718) is capable of reacting with 5-nitro-1,10-phenanthroline to form the complex [Pd(Piv)4Mn( nphen)] (IV) (CIF file CCDC No. 2217719).
- Keywords
- палладий марганец гетерометаллические комплексы синтез рентгеноструктурный анализ кристаллохимия
- Date of publication
- 01.12.2023
- Year of publication
- 2023
- Number of purchasers
- 0
- Views
- 12
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