RAS Chemistry & Material ScienceКоординационная химия Russian Journal of Coordination Chemistry

  • ISSN (Print) 0132-344X
  • ISSN (Online) 3034-5499

Samarium(III) Complex Based on 5-Phenyl-2,2´-bipyridine with the Diethylenetriaminotetraacetic Acid Residue in the C6 Position: Synthesis, Crystal Structure, and Photophysical Properties

PII
10.31857/S0132344X24060012-1
DOI
10.31857/S0132344X24060012
Publication type
Article
Status
Published
Authors
Volume/ Edition
Volume 50 / Issue number 6
Pages
356-362
Abstract
New samarium complex of 5-phenyl-2,2´-bipyridine with the diethylenetriaminotetraacetic acid (DTTA) residue in the C6 position, [(L2)Sm2Na5(H2О)9(C2O4)]n (I), is synthesized. The structure of complex I is studied by XRD (CIF file CCDC no. 2217968). The complex in the crystal is found to be a onedimensional coordination polymer, and the 2,2´-bipyridine fragments do not chelate the Sm3+ cation. The complex is characterized by a luminescence response to the addition of an excess of zinc cations.
Keywords
комплексы самария(III) 2,2´-бипиридины диэтилентриаминотетрауксусная кислота люминесценция РСА координационный полимер
Date of publication
10.06.2024
Year of publication
2024
Number of purchasers
0
Views
37

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