RAS Chemistry & Material ScienceКоординационная химия Russian Journal of Coordination Chemistry

  • ISSN (Print) 0132-344X
  • ISSN (Online) 3034-5499

Scalable Approach for Grafting Qubit Candidates onto The Surface of MOF-808 Framework

PII
10.31857/S0132344X24090039-1
DOI
10.31857/S0132344X24090039
Publication type
Article
Status
Published
Authors
Volume/ Edition
Volume 50 / Issue number 9
Pages
557-565
Abstract
The development of quantum bits (qubits) is crucial for the progress of quantum technologies. Among various approaches, the qubits based on paramagnetic centers have decent advantages, including their diversity and possibilities of regular ordering, for example, within the structure of metal-organic frameworks (MOFs). In the present work a simple and scalable approach to obtain qubit candidates based on stable organic radical 3-carboxy-proxyl and MOF-808 framework has been demonstrated. Investigation of the obtained compounds with different radical amounts using electron paramagnetic resonance (EPR) demonstrates the presence of two fractions of radicals, which is supported by simulations. Sufficiently long phase memory time at room temperature for the radicals adsorbed into MOF (0.39 μs), as well as the observed Rabi nutations, allow considering this material as a platform for qubits design. The developed approach is capable of incorporating various amounts of paramagnetic centers into the MOF structure and can be employed to obtain other spin qubit candidates.
Keywords
металл-органические координационные полимеры квантовые биты электронный парамагнитный резонанс осцилляции Раби
Date of publication
08.09.2024
Year of publication
2024
Number of purchasers
0
Views
11

References

  1. 1. DiVincenzo D.P. // Fortschritte Der Phys. 2000, V. 48. № 9-11. P. 771.
  2. 2. Ladd T. D., Jelezko F., Laflamme R. et al. // Nature. 2010. V. 464. № 7285. P. 45.
  3. 3. Nakazawa S., Nishida S., Ise T. et al. // Angew. Chem. Int. Ed. 2012. V. 51. № 39. P. 9860.
  4. 4. Dolde F., Fedder H., Doherty M.W. et al. // Nat. Phys. 2011. V. 7. № 6. P. 459.
  5. 5. Atzori M., Sessoli R. // J. Am. Chem. Soc. 2019. V. 141. № 29. P. 11339.
  6. 6. Nielsen M.A., Chuang I.L. Quantum Computation and Quantum Information: 10th Anniversary. Cambridge Univ. Press, 2010.
  7. 7. Knill E., Laflamme R., Milburn G.J. // Nature. 2001. V. 409. № 6816. P. 46.
  8. 8. Bruzewicz C.D., Chiaverini J., McConnell R. et al. // Appl. Phys. Rev. 2019. V. 6. № 2. P. 021314.
  9. 9. Benhelm J., Kirchmair G., Roos C. F. et al. // Nat. Phys. 2008. V. 4. № 6. P. 463.
  10. 10. Devoret M.H., Schoelkopf R.J. // Science. 2013. V. 339. № 6124. P. 1169.
  11. 11. Siddiqi I. // Nat. Rev. Mater. 2021. V. 6. № 10. P. 875.
  12. 12. Kjaergaard M., Schwartz M. E., Braumüller J. et al. // Annu. Rev. Condens. Matter Phys. 2020. V. 11. № 1. P. 369.
  13. 13. Trauzettel B., Bulaev D. V., Loss D. et al. // Nat. Phys. 2007. V. 3. № 3. P. 192.
  14. 14. Doherty M.W., Manson N.B., Delaney P. et al. // Phys. Rep. 2013. V. 528. № 1. P. 1.
  15. 15. Togan E., Chu Y., Trifonov A.S. et al. // Nature. 2010. V. 466. № 7307. P. 730.
  16. 16. Hanson R., Awschalom D.D. // Nature. 2008. V. 453. № 7198. P. 1043.
  17. 17. Chatterjee A., Stevenson P., De Franceschi S. et al. // Nature Rev. Phys. 2021. V. 3. № 3. P. 157.
  18. 18. Yamabayashi T., Atzori M., Tesi L., et al. // J. Am. Chem. Soc. 2018. V. 140. № 38. P. 12090.
  19. 19. Fataftah M.S., Bayliss S.L., Laorenza D.W. et al. // J. Am. Chem. Soc. 2020. V. 142. № 48. P. 20400.
  20. 20. Starikova A.A., Starikov A.G., Minkin V.I. // Russ. J. Coord. Chem. 2017. V. 43. № 4. P. 197.
  21. 21. Zadrozny J.M., Gallagher A.T., Harris T.D. et al. // J. Am. Chem. Soc. 2017. V. 139. № 20. P. 7089.
  22. 22. Stamp P.C.E., Gaita-Ariño A. // J. Mater. Chem. 2009. V. 19. № 12. P. 1718.
  23. 23. Gaita-Ariño A., Luis F., Hill S. et al. // Nat. Chem. 2019. V. 11. № 4. P. 301.
  24. 24. Poryvaev A.S., Gjuzi E., Polyukhov D.M. et al. // Angew. Chem. Int. Ed. 2021. V. 60. № 16. P. 8683.
  25. 25. Oanta A.K., Collins K.A., Evans A.M. et al. // J. Am. Chem. Soc. 2023. V. 145. № 1. P. 689.
  26. 26. Wakizaka M., Gupta S., Wan Q. et al. // Chem. Eur. J. 2023. V. 30. № 12. Art. e202304202.
  27. 27. Yu C.J., Krzyaniak M.D., Fataftah M.S., et al. // Chem. Sci. 2019. V. 10. № 6. P. 1702.
  28. 28. Sun L. et al. // J. Am. Chem. Soc. 2022. V. 144. № 41. P. 19008.
  29. 29. Альтшулер С.А., Козырев Б.М. // Успехи физ. наук. 1957. V. 63. № 11. P. 533.
  30. 30. Weil J.A., Bolton J.R. Electron Paramagnetic Resonance: Elementary Theory and Practical Applications. Wiley, 2007.
  31. 31. Schweiger A., Jeschke G. Principles of Pulse Electron Paramagnetic Resonance. Oxford University Press, 2001.
  32. 32. Zadrozny J.M., Niklas J., Poluektov O.G. et al. // ACS Cent Sci. 2015. V. 1. № 9. P. 488.
  33. 33. Schäfter D., Wischnat J., Tesi L. et al. // Adv. Mater. 2023. V. 35. № 38. P. 2302114.
  34. 34. Liu X. et al. // Chem. Mater. 2021. V. 33. № 4. P. 1444.
  35. 35. Yan X., Wang K., Xu X. et al. // Inorg. Chem. 2018. V. 57. № 14. P. 8033.
  36. 36. Furukawa H., Gándara F., Zhang Y.-B. et al. // J. Am. Chem. Soc. 2014. V. 136. № 11. P. 4369.
  37. 37. Paletta J.T., Pink M., Foley B. et al. // Org. Lett. 2012. V. 14. № 20. P. 5322.
  38. 38. Stoll S., Schweiger A. // J. Magn. Res. 2006. V. 178. № 1. P. 42.
  39. 39. Jiang J., Gándara F., Zhang Y.-B. et al. // J. Am. Chem. Soc. 2014. V. 136. № 37. P. 12844.
  40. 40. Peng Y., Huang H., Zhang Y. et al. // Nat. Commun. 2018. V. 9. № 1. P. 187.
  41. 41. Li J., Huang H., Xue W. et al. // Nat. Catal. 2021. V. 4. № 8. P. 719.
  42. 42. Lyu H., Chen O.I.-F., Hanikel N. et al. // J. Am, Chem. Soc. 2022. V. 144. № 5. P. 2387.
  43. 43. Kuzhelev A.A., Strizhakov R. K., Krumkacheva O. A. et al. // J. Magn. Res. 2016. V. 266. P. 1.
  44. 44. Chernova D.A., Vorobiev A.K. // J. Polym. Sci. B. 2009. V. 47. № 1. P. 107.
  45. 45. Rajca A., Kathirvelu V., Roy S.K. et al. // Chem. Eur. J. 2010. V. 16. № 19. P. 5778.
  46. 46. Ivanov M.Yu., Prikhod′ko S.A., Bakulina O.D. et al. // Molecules. 2021. V. 26. № 19.
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