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RAS Chemistry & Material ScienceКоординационная химия Russian Journal of Coordination Chemistry

  • ISSN (Print) 0132-344X
  • ISSN (Online) 3034-5499

Imidazolium Salts with Heterometallic Complex Anions [Co₂Li₂(Piv)₈]²⁻: Synthesis, Structures, and Magnetic Properties

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PII
10.31857/S0132344X24110047-1
DOI
10.31857/S0132344X24110047
Publication type
Article
Status
Published
Authors
S. N. Melnikov
  • Affiliation: Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences
Volume/ Edition
Volume 50 / Issue number 11
Pages
787-798
Abstract
Imidazolium salts with complex anions [Co₂Li₂(Piv)₈]²⁻ are formed as undesirable products of the reactions of heterometallic compound [Co₂Li₂(Piv)₆(Py)₂] with N-heterocyclic carbenes ItBu and IPr. The study of the magnetic properties of complex (HItBu)₂[Co₂Li₂(μ₂-Piv)₆(Ƙ¹-Piv)₂] shows that this compound is a single molecule magnet. Slow magnetic relaxation in the complex occurs due to a combination of the direct and Raman mechanisms.
Keywords
карбоксилатные лиганды гетерометаллические комплексы кобальт(II) литий(I) молекулярная структура магнитные свойства
Date of publication
15.11.2024
Year of publication
2024
Number of purchasers
0
Views
6

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