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RAS Chemistry & Material ScienceКоординационная химия Russian Journal of Coordination Chemistry

  • ISSN (Print) 0132-344X
  • ISSN (Online) 3034-5499

Nickel(II) Complex with the Bis(phenolate) Pincer N-Heterocyclic Carbene Ligand: Synthesis, Structure, and Properties

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PII
S3034549925010011-1
DOI
10.7868/S3034549925010011
Publication type
Article
Status
Published
Authors
Z. N. Gafurov
  • Affiliation: Arbuzov Institute of Organic and Physical Chemistry, Kazan Scientific Center, Russian Academy of Sciences
M. V. Kozlova
  • Affiliation: Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences
Dmitry Yakhvarov
  • Affiliation: Butlerov Institute of Chemistry, Kazan (Volga Region) Federal University
Volume/ Edition
Volume 51 / Issue number 1
Pages
3-11
Abstract
The nickel(II) complex Ni(L)Py (I) (L is 1,3-bis(3,5-di-tert-butyl-2-phenolato)-5,5-dimethyl-(4,6-dihydropyrimidin-2-ylidene)) containing the dianionic bonded N-heterocyclic carbene (NHC) bis(phenolate) ligand is synthesized. In the presence of a stronger base (4-dimethylaminopyridine (DMAP)), the exchange reaction occurs with the replacement of pyridine in complex I by the DMAP molecule to form complex Ni(L)(DMAP) (II), the crystal structure of which is determined by XRD. The synthesized compounds are characterized by elemental analysis, mass spectrometry, and NMR spectroscopy. The spectral characteristics of the compounds are studied.
Keywords
комплексы никеля (II) N-гетероциклические карбеновые лиганды пинцерные лиганды
Date of publication
17.01.2025
Year of publication
2025
Number of purchasers
0
Views
31

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