- PII
- S3034549925010076-1
- DOI
- 10.7868/S3034549925010076
- Publication type
- Article
- Status
- Published
- Authors
- Volume/ Edition
- Volume 51 / Issue number 1
- Pages
- 60-71
- Abstract
- A new redox-active cobalt(III) complex with a catechol dianion and two 4,4’-dimethoxy-2,2’-bipyridine ligands was synthesized. The reduction of the complex with ascorbic acid in an inert atmosphere was studied by NMR spectroscopy in situ. The reaction followed the first-order kinetics with respect to the starting complex, had a rate constant of 1.1 × 10−3 s−1, and was accompanied by the release of catechol, which served as a model drug.
- Keywords
- in situ спектроскопия ядерного магнитного резонанса пирокатехин комплексы кобальта редокс-активируемая доставка лекарственных препаратов
- Date of publication
- 17.01.2025
- Year of publication
- 2025
- Number of purchasers
- 0
- Views
- 61
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