- PII
- S3034549925040072-1
- DOI
- 10.7868/S3034549925040072
- Publication type
- Article
- Status
- Published
- Authors
- Volume/ Edition
- Volume 51 / Issue number 4
- Pages
- 277-284
- Abstract
- It was found that monovalent thulium iodide TmI in the TmIx mixture reacts with hydrogen at 200°C and atmospheric pressure, forming a hydrogenation product [TmIxH], which is confirmed by the reaction with (C6F5)3GeBr, leading to the formation of (C6F5)3GeН. In the reaction with nitrogen at 450°C, a mixture is formed containing diiodide TmI2 and a product of the composition [Tm4IN], containing a Tm–N valence bond. TmI in the TmIx mixture also reacts with phenol and phenylacetylene. In the first case, a difficult-to-separate mixture of iodide phenolates TmIx(OPh)y is formed. The reaction with PhC≡CH leads to the formation of styrene, diphenylbenzene and a mixture of triphenylbenzenes. In the reaction of TmIx with СО2, trivalent thulium iodioxalate (C2O4)TmI(DМЕ).was isolated with a high yield.
- Keywords
- одновалентный тулий иодид тулия реакционная способность магнитный момент рентгенофазовый анализ
- Date of publication
- 15.04.2025
- Year of publication
- 2025
- Number of purchasers
- 0
- Views
- 50
References
- 1. Fong F.K., Cape J.A., Wong E.Y. // Phys. Rev. 1966. V. 151. P. 299. https://doi.org/10.1103/PhysRev.151.299
- 2. Arnold P.L., Cloke F.G.N., Nixon J.F. // Chem. Commun. 1998. P. 797. https://doi.org/10.1039/A800089A
- 3. Li W.-L., Chen T.-T., Chen W.-J. et al. // Nature Commun. 2021. V. 12. P. 6467. https://doi.org/10.1038/s41467-021-26785-9
- 4. Ka‶ning M., Hitzschke L., Schalk B. et al. // J. Phys. D. 2011. V. 44. P. 224005. https://doi.org/10.1088/0022-3727/44/22/224005
- 5. Ka‶ning M., Schalk B., Schneidenbach H. // J. Phys. D. 2007. V. 40. P. 3815. https://doi.org/10.1088/0022-3727/40/13/S01
- 6. Бочкарев М.Н., Фагин А.А., Хорошеньков Г.В. // Изв. АН. Сер. хим. 2002. С. 1757 (Bochkarev M.N., Fagin A.A., Khoroshenkov G.V. // Russ. Chem. Bull. Int. Ed. 2002. V. 51. P. 1909). https://doi.org/10.1023/A:1021364804963
- 7. Фагин А.А., Бухвалова С.Ю., Бочкарев М.Н. // Коорд. химия. 2022. Т. 11. С. 686 (Fagin A.A., Bukhvalova S.Yu., Bochkarev M.N. // Russ. J. Coord. Chem. 2022. V. 48. № 11. P. 741). https://doi.org/10.1134/S1070328422110045
- 8. Фагин A.A., Бухвалова С.Ю., Куропатов В.А., Бочкарев М.Н. // Коорд. химия. 2023. T. 49. № 5. C. 303 (Fagin A.A., Bukhvalova S.Yu., Kuropatov V.A., Bochkarev M.N. // Russ. J. Coord. Chem. 2023. V. 49. № 5. P. 299). https://doi.org/10.31857/S0132344X22600357
- 9. Fagin A.A., Bukhvalova S.Yu., Kovylin R.S., Bochkarev M.N. // Russ. J. General. Chem. 2023. V. 93. Suppl. 3. P. S840. https://doi.org/10.1134/S1070363223160235
- 10. Бочкарев М.Н., Протченко А.П. // Приборы и техника эксперимента. 1990. № 1. С. 194.
- 11. Бочкарев М.Н., Фагин А.А., Федюшкин И.Л. и др. // Изв. АН. Сер. хим. 1999. № 9. С. 1084 (Bochkarev M.N., Fagin A.A., Fedushkin I.L. et al. // Russ. Chem. Bull. 1999. № 9. P. 1782). https://doi.org/10.1007/BF02494829
- 12. Doebelin N., Kleeberg R. // J. Appl. Cryst. 2015. V. 48. P. 1573. https://doi.org/10.1107/S1600576715014685
- 13. Гражулис С., Шатейнер Д., Даунс Р.Т., Йокочи А.Ф. и др. // Журн. прикл. кристаллографии. 2009. Т. 42. № 4. С. 726. https://doi.org/10.1107/S0021889809016690
- 14. Harris I.R., Raynor G.V. // J. Less-Common Met. 1969. V. 17. P. 336. https://doi.org/10.1016/0022-5088 (69)90154-4
- 15. Wyckoff R.W.G. Crystal Structures. New York: Interscience Publishers, 1963. V. 1. P. 239.
- 16. Бочкарев М.Н., Логунов А.А., Бурин М.Е. // Изв. АН. Сер. хим. 2007. С. 1887 (Bochkarev M.N., Logunov A.A., Burin M.E. // Russ. Chem. Bull. Int. Ed. V. 56. P. 1953). https://doi.org/10.1007/s11172-007-0303-x
