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RAS Chemistry & Material ScienceКоординационная химия Russian Journal of Coordination Chemistry

  • ISSN (Print) 0132-344X
  • ISSN (Online) 3034-5499

Binuclear diphenyltin(IV) complexes with salicylaldimine ligands. Synthesis, structure, electrochemical properties

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PII
S3034549925060011-1
DOI
10.7868/S3034549925060011
Publication type
Article
Status
Published
Authors
E.N. Nikolaevskaya
  • Affiliation: Zelinsky Institute of Organic Chemistry Russian Academy of Sciences
Volume/ Edition
Volume 51 / Issue number 6
Pages
355-365
Abstract
New binuclear tin(IV) complexes based on salicylic Schiff bases and diphenyltin oxide Ph2SnO were obtained. The structures of the complexes were confirmed by 1H, 13C and 119Sn NMR spectroscopy and X-ray diffraction analysis (CCDC 2433411). UV-Vis spectroscopy of complexes 1–4 showed that a bathochromic shift of all ligand absorption bands was observed upon complexation with the metal fragment. The ability of complexes 1–4 to undergo electrochemical transformations was investigated by cyclic voltammetry. In all cases, the oxidation and reduction of the complexes are irreversible. In the cases of complexes 2–4 with a conjugated bridge, the oxidation of two metal fragments occurs at one potential, whereas complex 1 with an unconjugated adipic bridge has two peaks on the oxidation curve at different potentials, which is probably since the oxidation of two different ‘ends’ of the molecule occurs at different potentials.
Keywords
основания Шиффа комплексы олова ЯМР-спектроскопия циклическая вольтамперометрия рентгеноструктурный анализ
Date of publication
16.06.2025
Year of publication
2025
Number of purchasers
0
Views
79

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