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RAS Chemistry & Material ScienceКоординационная химия Russian Journal of Coordination Chemistry

  • ISSN (Print) 0132-344X
  • ISSN (Online) 3034-5499

Design of an Unsymmetrical PCN Nickel(II) Pincer Complex Based on 2,3,4,5-Tetraphenyl-1-Monophosphole

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PII
S3034549925080024-1
DOI
10.7868/S3034549925080024
Publication type
Article
Status
Published
Authors
Z. N. Gafurov
  • Affiliation: Arbuzov Institute of Organic and Physical Chemistry, FRC Kazan Scientific Center, Russian Academy of Sciences
Dmitry Yakhvarov
  • Affiliation: Arbuzov Institute of Organic and Physical Chemistry, FRC Kazan Scientific Center, Russian Academy of Sciences
Volume/ Edition
Volume 51 / Issue number 8
Pages
501-509
Abstract
A new unsymmetrical PCN pincer ligand, -ethyl--(3-((2,3,4,5-tetraphenyl-1-phosphol-1-yl))methyl) benzylpethanamine, combining different donors (amine and phosphole groups), has been synthesized. The ligand was obtained in four steps with a good overall yield (49%), using commercially available reagents as starting materials. Based on the obtained ligand, a design of an unsymmetrical nickel(II) pincer complex was proposed. Quantum-chemical calculations of the molecular structure of the complex show the formation of weak Ni–P bonds and the manifestation of a weak -influence of the phosphole group with respect to the amine group, which distinguishes this complex from its analogs, PCN complexes based on dialkylphosphines.
Keywords
комплексы никеля(II) пинцерные лиганды фосфолы
Date of publication
15.08.2025
Year of publication
2025
Number of purchasers
0
Views
33

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