- PII
- S30345499S0132344X25050042-1
- DOI
- 10.7868/S3034549925050042
- Publication type
- Article
- Status
- Published
- Authors
- Volume/ Edition
- Volume 51 / Issue number 5
- Pages
- 315-326
- Abstract
- By interaction of compounds Zn(II) and L-arginine (L-Arg) the chelated complexes [Zn(L-arg)2(H2O)] (I) and [[Zn(L-arg)2(H2O)](SO4)]2- (II) (L-arg is a deprotonated form of L-Arg) were synthesized. The structure of the obtained complexes was established by IR spectroscopy by comparing the experimental and theoretical IR spectra using quantum chemical modeling. Complexes I and II were studied as chiral selectors of enantioselective voltammetric sensors. It was shown that I exhibits better enantioselective compared to II. By DFT method, it was found that the difference in the exhibited enantioselectivity of complexes I and II can be due of the geometric isomerism of chelate compounds and the peculiarities of the coordination of the obtained complexes with the analyte molecule.
- Keywords
- хелатные комплексы на основе Z-аргинина и ионов Zn(II) ИК-спектроскопия хиральные сенсоры энантиоселективность квантово-химическое моделирование
- Date of publication
- 15.05.2025
- Year of publication
- 2025
- Number of purchasers
- 0
- Views
- 37
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