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RAS Chemistry & Material ScienceКоординационная химия Russian Journal of Coordination Chemistry

  • ISSN (Print) 0132-344X
  • ISSN (Online) 3034-5499

Complexes R2Sn(IV)L with O,N,O'-Donor Schiff Bases: Synthesis, Structures, and Redox Properties

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PII
10.31857/S0132344X22600266-1
DOI
10.31857/S0132344X22600266
Publication type
Status
Published
Authors
I. V. Smolyaninov
  • Affiliation:
    Astrakhan State Technical University, Astrakhan, Russia
    Razuvaev Institute of Organometallic Chemistry, Russian Academy of Sciences, Nizhny Novgorod, Russia
Volume/ Edition
Volume 49 / Issue number 3
Pages
138-156
Abstract
New tin(IV) complexes with O,N,O'-donor Schiff bases (L1H2–L4H2) of the (Ln)SnR2 type (R = Ph (I–III), Et (IV–VII)) are synthesized and characterized. The molecular structures of compounds I–III, VI, and VII in the crystalline form are determined by X-ray diffraction (XRD) (CIF files CCDC nos. 2181140 (I), 2181142 (II), 2181143 (III∙CH3CN), 2181141 (VI), and 2181139 (VII)). Tin complexes I–III and VI are mononuclear pentacoordinate compounds. Crystalline complex VII forms dimers via the pairwise bridging coupling between the oxygen and tin atoms of the mononuclear fragments. The redox-active ligand in the synthesized compounds exists as the iminobis(phenolate) dianion. The electrochemical properties of free ligands and complexes I–VII are studied. In the case of compounds I, II, IV, and V with tert-butyl substituents in the redox-active ligand, the formation of relatively stable monocationic and monoanionic species is electrochemically detected for the first time. The presence of the electroactive nitro group results in the destabilization of the oxidized forms of the complexes and induces the appearance of an additional peak in the cathodic range. The energy gaps between the frontier redox orbitals are determined by the electrochemical and spectral methods. The obtained parameters are close and vary in a range of 2.43–2.68 eV.
Keywords
комплексы олова(IV) редокс-активные основания Шиффа рентгеноструктурный анализ циклическая вольтамперометрия редокс-превращения
Date of publication
01.03.2023
Year of publication
2023
Number of purchasers
0
Views
10

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