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RAS Chemistry & Material ScienceКоординационная химия Russian Journal of Coordination Chemistry

  • ISSN (Print) 0132-344X
  • ISSN (Online) 3034-5499

Bromoantimonates(III) vs. Bromobismuthates(III): Differences in the Tendency for the Formation of Polynuclear Complexes

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PII
10.31857/S0132344X22600400-1
DOI
10.31857/S0132344X22600400
Publication type
Status
Published
Authors
Sergey Adonin
  • Affiliation: Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences, Novosibirsk, Russia
Volume/ Edition
Volume 49 / Issue number 6
Pages
341-346
Abstract
Pyridine-based Sb(III) bromide complexes with doubly charged cations, (PyC3)3[Sb2Br9]2 (I), (PyC4)[Sb2Br8] (II), (PyC5)2[α-Sb4Br16] (III), (PyC6)2[Sb2Br10] (IV), (4-MePyC2)2[Sb2Br10] (V), (4‑MePyC3)2[α-Sb4Br16] (VI), and (4-MePyC5)2[α-Sb4Br16] (VII), were synthesized and characterized by X-ray diffraction (CCDC nos. 2204718–2204724). The structures of these compounds were compared with the structures of related bromobismuthates(III).
Keywords
сурьма висмут галогенидные комплексы полиядерные комплексы рентгеноструктурный анализ
Date of publication
01.06.2023
Year of publication
2023
Number of purchasers
0
Views
13

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