RAS Chemistry & Material ScienceКоординационная химия Russian Journal of Coordination Chemistry

  • ISSN (Print) 0132-344X
  • ISSN (Online) 3034-5499

Second Example of a Cubane-Like Nickel(II) Complex in a Series of N-Derivatives of Taurine

PII
10.31857/S0132344X2260045X-1
DOI
10.31857/S0132344X2260045X
Publication type
Status
Published
Authors
Volume/ Edition
Volume 49 / Issue number 7
Pages
441-448
Abstract
A new homometallic cubane-like nickel(II) complex based on N-2-(2-pyridyl)ethyl-2-aminoethanesulfonic acid [Ni4L4(OH)4]·2H2O (I) is synthesized, and its structure is studied by X-ray diffraction (XRD) (CIF file CCDC no. 2211359). In crystals of the complex, the metallocenters are joined into tetrahedra with the Ni…Ni distances (3.144–3.201 Å) supplemented to cubanes by the μ3-bridging oxygen atoms of the hydroxy groups. The coordination environment of each metallocenter is a distorted octahedron. The ligand is deprotonated, exists in the facial conformation, and performs the tridentate function to form two six-membered conjugated chelate cycles.
Keywords
кубаноподобный комплекс никеля(II) N-производные таурина комплексообразование рентгеноструктурного анализ
Date of publication
01.07.2023
Year of publication
2023
Number of purchasers
0
Views
13

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