- PII
- 10.31857/S0132344X22600497-1
- DOI
- 10.31857/S0132344X22600497
- Publication type
- Status
- Published
- Authors
- Volume/ Edition
- Volume 49 / Issue number 6
- Pages
- 367-374
- Abstract
- The reaction of 2,6-di(tert-butyl)anthracene with potassium graphite and monocyclopentadienyllutetium dichloride tetrahydrofuranate in THF gave the anthracenide complex [(η5-C5H5)Lu(η2-2,6-tBu2C14H8)(THF)2] (I), which was studied by X-ray diffraction (CCDC no. 2215512). Complex I crystallizes in the orthorhombic space group P212121. The structural rigidity of the Lu(O)2Cp(anthracene) crystallographic node was demonstrated. The retention of the structure of complex I in solution was confirmed by NMR techniques.
- Keywords
- редкоземельные элементы лютеций антрацен рентгеноструктурный анализ
- Date of publication
- 01.06.2023
- Year of publication
- 2023
- Number of purchasers
- 0
- Views
- 11
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