- PII
- 10.31857/S0132344X22600606-1
- DOI
- 10.31857/S0132344X22600606
- Publication type
- Status
- Published
- Authors
- Volume/ Edition
- Volume 49 / Issue number 8
- Pages
- 458-465
- Abstract
- A possibility of generating a high degree of spin polarization of 13C and 15N nuclei in the cyanide ion, which forms the coordination bond with the metal ion, using parahydrogen is demonstrated for the first time for the new iridium carbene complex as an example. The spin–spin interaction constants in the synthesized complex and the structure of the hydride intermediate are determined by an analysis of the 13С NMR spectra detected using broadband and selective heteronuclear decoupling. The cyanide ion is shown to coordinate to the metal ion by the carbon atom in one of two equatorial positions, and two pyridine molecules are arranged in the axial and equatorial positions. The signal amplification factors for 13С and 15N nuclei of the cyanide anion (5665 and –49 555, respectively) are estimated by NMR spectroscopy of the polarized substrate using the SABRE method from an ultralow magnetic field of 0.5 μT. This amplification corresponds to 15.5% polarization of nitrogen nuclei achieved within several seconds at room temperature.
- Keywords
- спектроскопия ЯМР параводород гиперполяризация комплексы иридия карбеновые лиганды усиление сигнала индуцированная параводородом гиперполяризация ядер
- Date of publication
- 01.08.2023
- Year of publication
- 2023
- Number of purchasers
- 0
- Views
- 12
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