- PII
- 10.31857/S0132344X22600643-1
- DOI
- 10.31857/S0132344X22600643
- Publication type
- Status
- Published
- Authors
- Volume/ Edition
- Volume 49 / Issue number 7
- Pages
- 422-430
- Abstract
- The exchange reactions of 4,6-di-tert-butylpyrocatechols containing in position 3 different N‑aryliminomethyl groups (aryl is p-halophenyl; halogen is fluorine (I), chlorine (II), bromine (III), and iodine (IV); p-tolyl (V)) with copper(II) acetate in a molar ratio of 2 : 1 afford planar square copper(II) o‑iminophenolate complexes of the general formula [(R-CatH)2Cu], where R is the aryl substituent in the Ar–N=CH group. The molecular structures of complexes I, III, and V in the crystalline state are determined by X-ray diffraction (XRD) (CIF files CCDC nos. 2227448 (I), 2226727 (III), and 2227449 (V)). The electrochemical properties of compounds I–V are studied by cyclic voltammetry.
- Keywords
- пирокатехин основание Шиффа медь(II) циклическая вольтамперометрия рентгеноструктурный анализ
- Date of publication
- 01.07.2023
- Year of publication
- 2023
- Number of purchasers
- 0
- Views
- 11
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