- PII
- 10.31857/S0132344X24040063-1
- DOI
- 10.31857/S0132344X24040063
- Publication type
- Article
- Status
- Published
- Authors
- Volume/ Edition
- Volume 50 / Issue number 4
- Pages
- 278-284
- Abstract
- The reactions of equimolar amounts of alkyltriphenylphosphonium bromide with arenesulfonic acids in an aqueous-acetone solution afford alkyltriphenylphosphonium arenesulfonates [Ph3PCH2ОMe][OSO2C6H3(OH-4)(COOH-3)] (I), [Ph3PCH2СN][OSO2C6H4(COOH)-2] (II), [Ph3PCH2C(O)Me][OSO2С6H4(COOH-2] (III), and [Ph3PCH2C(O)Me][OSO2Naft-1] (IV). According to the X-ray diffraction (XRD) data, the crystals of compounds I−IV have ionic structures with tetrahedral alkyltriphenylphosphonium cations (P−С 1.7820(19)−1.8330(20) A, CPC 05.37(10)°−112.09(12)°) and arenesulfonate anions. The crystal of compound I contains hydrogen bonds (S=O∙∙∙H−OC(O) 1.87 A) linking the arenesulfonate anions into chains. The structural organization of the crystals of compounds I−IV is mainly formed due to numerous weak hydrogen bonds between the cations and anions, for instance, S=O∙∙∙H−Car (2.29−2.70 A), C=O∙∙∙H–C (2.48 and 2.59 A), and N∙∙∙H–C (2.62−2.68 A).
- Keywords
- аренсульфонат алкилтрифенилфосфония синтез строение рентгеноструктурные исследования
- Date of publication
- 15.04.2024
- Year of publication
- 2024
- Number of purchasers
- 0
- Views
- 36
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