Везде

RAS Chemistry & Material ScienceКоординационная химия Russian Journal of Coordination Chemistry

  • ISSN (Print) 0132-344X
  • ISSN (Online) 3034-5499

Monomeric and Polymeric Cyclopentadienyl Dysprosium Complexes Based on the Acenaphthene-1,2-diimine Ligand

You can
PII
10.31857/S0132344X24060024-1
DOI
10.31857/S0132344X24060024
Publication type
Article
Status
Published
Authors
N. L. Bazyakina
  • Affiliation: Razuvaev Institute of Organometallic Chemistry, Russian Academy of Sciences
Volume/ Edition
Volume 50 / Issue number 6
Pages
363-373
Abstract
The reaction of [(Dpp-bian)DyI(Dme)2] (Dpp-bian is 1,2-bis[(2,6-diisopropylphenyl)imino]acenaphthene, Dme is CH3OCH2CH2OCH3) with Cp*K (Cp* is C5Me5) in toluene followed by crystallization from benzene affords crystals of the 1D coordination polymer [(Dpp-bian)DyIKCp*]n (I)•2.6C6H6 (26%) and crystals of the monomeric complex [(Dpp-bian)DyCp*(Dme)] (II)•1.5C6H6 (12%). The same reaction in 1,2-dimethoxyethane followed by crystallization from benzene makes it possible to isolate only complex II•1.5C6H6 in a yield of 48%. The synthesized compounds are characterized by IR and UV spectroscopy and elemental and thermogravimetric analyses. Their molecular structures are determined by XRD (CIF files CCDC nos. 2298407 (I) and 2298408 (II)).
Keywords
диспрозий циклопентадиенил 1,2-бис(арилимино)аценафтен координационный полимер редокс-активный лиганд
Date of publication
10.06.2024
Year of publication
2024
Number of purchasers
0
Views
11

References

  1. 1. Furukawa H., Cordova K.E., O´Keeffe M. et al. // Science. 2013. V. 341. № 6149. P. 1230444-1.
  2. 2. Lin R.-B., Xiang S., Zhou W. et al. // Chem. 2020. V. 6. № 2, P. 337.
  3. 3. Li J.-R., Kuppler R.J., Zhou H.-C. // Chem. Soc. Rev. 2009. V. 38. № 5. P. 1477.
  4. 4. Li J.-R., Sculley J., Zhou. H.-C. // Chem. Rev. 2012. V. 112. № 2. P. 869
  5. 5. Lee J., Farha O.K., Roberts J. et al. // Chem. Soc. Rev. 2009. V. 38. № 5. P. 1450.
  6. 6. Agafonov M.A., Alexandrov E.V., Artyukhova N.A. et al. // J. Struct. Chem. 2022. V. 63. P. 671.
  7. 7. Kurmoo M. // Chem. Soc. Rev. 2009. V. 38. № 5. P. 1353.
  8. 8. Lustig W.P., Mukherjee S., Rudd N.D. et al. // Chem. Soc. Rev. 2017. V. 46. № 11. P. 3242.
  9. 9. Cui Y., Yue Y., Qian G. et al. // Chem. Rev. 2012. V. 112. № 2. P. 1126.
  10. 10. Rocha J., Carlos L.D., Paz F.A.A. et al. // Chem. Soc. Rev. 2011. V. 40. № 2. P. 926.
  11. 11. Bazyakina N.L., Makarov V.M., Ketkov S.Yu. et al. // Inorg. Chem. 2021. V. 60. № 5. P. 3238.
  12. 12. D´Alessandro D.M. // Chem. Commun. 2016. V. 52. № 58. P. 8957.
  13. 13. Calbo J., Golomb M.J., Walsh A. // J. Mater. Chem. A. 2019. № 28. V. 7. P. 16571.
  14. 14. Kharitonov A.D., Trofimova O.Y., Meshcheryakova I.N. et al. // CrystEngComm. 2020. V. 22. № 28. P. 4675.
  15. 15. Fedushkin I.L., Skatova A.A., Chudakova V.A. et al. // Angew. Chem. Int. Ed. 2003. V. 42. № 28. P. 3294.
  16. 16. Fedushkin I.L., Skatova A.A., Chudakova V.A. et al. // Eur. J. Inorg. Chem. 2003. V. 2003. № 18. P. 3336.
  17. 17. Lukoyanov A.N., Fedushkin I.L., Hummert M. et al. // Russ. Chem. Bull. 2006. V. 55. P. 422.
  18. 18. Fedushkin I.L., Lukoyanov A.N., Tishkina A.N. et al. // Chem. Eur. J. 2010. V. 16. № 25. P. 7563.
  19. 19. Fedushkin I.L., Maslova O.V., Baranov E.V. et al. // Inorg. Chem. 2009. V. 48. № 6. P. 2355.
  20. 20. Fedushkin I.L., Maslova O.V., Hummert M. et al. // Inorg. Chem. 2010. V. 49. № 6. P. 2901.
  21. 21. Fedushkin I.L., Skatova A.A., Yambulatov D.S. et al. // Russ. Chem. Bull. 2015. V. 64. P. 38.
  22. 22. Fedushkin I.L., Lukoyanov A.N., Baranov E.V. // Inorg. Chem. 2018. V. 57. № 8. P. 4301.
  23. 23. Fedushkin I.L., Lukina D.A., Skatova A.A. et al. // Chem. Commun. 2018. V. 54. № 92. P. 12950.
  24. 24. Fedushkin I.L., Lukoyanov A.N., Baranov E.V. // Inorg. Chem. 2018. V. 57. № 8. P. 4301.
  25. 25. Lukina D.A., Skatova A.A., Lukoyanov A.N. et al. // Dalton Trans. 2020. V. 49. № 9. P. 2941.
  26. 26. Lukina D.A., Skatova A.A., Sokolov V.G. et al. // Dalton Trans. 2020. V. 49. № 41. P. 14445.
  27. 27. Sokolov V.G., Lukina D.A., Skatova A.A. et al. // J. Struct. Chem. 2023. V. 64. № 9. P. 1724.
  28. 28. Fedushkin I.L., Maslova O.V., Morozov A.G. et al. // Angew. Chem. Int. Ed. 2012. V. 51. № 42. P. 10584.
  29. 29. Bazyakina N.L., Moskalev M.V., Rumyantcev R.V. et al. // Russ. Chem. Bull. 2023. V. 72. P. 507.
  30. 30. Apostolidis C., Deacon G.B., Dornberger E. et al. // Chem. Commun. 1997. № 11. P.1047.
  31. 31. Schumann H., Heim A., Demtschuk J. et al. // Organometallics. 2003. V. 22. № 1. P.118.
  32. 32. Sulway S.A., Layfield R.A., Tuna F. et al. // Chem. Commun. 2012. V. 48. № 10. P. 1508.
  33. 33. Lamberts W., Lueken H. // Inorg. Chim. Acta. 1987. V. 132. № 1. P. 119.
  34. 34. Evans W.J., Rego D.B., Ziller J.W. et al. // Organometallics 2007. V. 26. № 19. P. 4737.
  35. 35. Sokolov V.G., Lukina D.A., Skatova А.А. et al. // Russ. Chem. Bull. 2021. V. 70. P. 2119.
  36. 36. Paulovicova A.A., El-Ayaan U., Shibayama K. et al. // Eur. J. Inorg. Chem. 2001. V. 2001. №. 10. P. 2641.
  37. 37. Rigaku Oxford Diffraction. (2021). CrysAlis Pro software system, version 1.171.41.122a, Rigaku Corporation, Wroclaw, Poland.
  38. 38. Sheldrick G.M. // Acta Crystallogr. A. 2015. V. 71. P. 3.
  39. 39. Sheldrick G.M. // Acta Crystallogr. С. 2015. V. 71. P. 3.
  40. 40. Spek A.L. // Acta Crystallogr. C. 2015. V. 71. P. 9.
  41. 41. Dodonov V.A., Makarov V.M., Zemnyukova M.N. et al. // Organometallics. 2023. V. 42. № 18. P. 2558.
  42. 42. Fedushkin I.L., Skatova A.A., Chudakova V.A. et al. // Eur. J. Inorg. Chem. 2004. V. 2004. № 2. P. 388.
  43. 43. Skatova A.A., Yambulatov D.S., Fedyushkin I.L. et al. // Russ. J. Coord. Chem. 2018. V. 44. P. 400.
  44. 44. Long J., Tolpygin A.O., Cherkasov A.V. et al. // Organometallics. 2019. V. 38. P. 748.
  45. 45. Woen D.H., Kotyk C.M., Mueller T.J. et al. // Organometallics. 2017. V. 36. № 23. P. 4558.
  46. 46. Janiak C. // J. Chem. Soc. Dalton Trans. 2000. P. 3885.
QR
Translate

Индексирование

Scopus

Scopus

Scopus

Crossref

Scopus

Higher Attestation Commission

At the Ministry of Education and Science of the Russian Federation

Scopus

Scientific Electronic Library