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RAS Chemistry & Material ScienceКоординационная химия Russian Journal of Coordination Chemistry

  • ISSN (Print) 0132-344X
  • ISSN (Online) 3034-5499

Dynamic Magnetic Susceptibility Method in Studies of Coordination Compounds

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PII
10.31857/S0132344X24070011-1
DOI
10.31857/S0132344X24070011
Publication type
Article
Status
Published
Authors
N. N. Efimov
  • Affiliation: Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences
Volume/ Edition
Volume 50 / Issue number 7
Pages
413-428
Abstract
The measurement of the dynamic magnetic susceptibility is a universal method, which is used for the evaluation of magnetic properties of single molecule magnets by scientists all over the world. An information in the Russian scientific literature that can be useful for practical mastering of this method is presently insufficient. To fill this gap, in this work we present a detailed procedure of a magnetochemical experiment for observing slow magnetic relaxation in coordination compounds of 3d- and 4f-element ions and the complete characterization of the dynamics of the magnetic behavior. Special attention is given to usually omitted but important details related to all stages of studying the magnetic relaxation dynamics. The main variants of sample preparation are described, the logics of the construction of a measuring sequence and the procedure of experimental data processing are discussed, and advantages and drawbacks of some programs of the calculation of magnetic relaxation dynamics data are considered. The main concepts and equations used in experimental data analysis are presented, and the primary conclusions that can be made from the obtained results are proposed.
Keywords
магнитные свойства динамическая магнитная восприимчивость методики проведения эксперимента магнитная релаксация молекулярный магнетизм
Date of publication
15.07.2024
Year of publication
2024
Number of purchasers
0
Views
11

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