- PII
- 10.31857/S0132344X24070028-1
- DOI
- 10.31857/S0132344X24070028
- Publication type
- Article
- Status
- Published
- Authors
- Volume/ Edition
- Volume 50 / Issue number 7
- Pages
- 429-437
- Abstract
- The reaction of new bidentate ligand, 1-(5-hydroxy-1-methyl-3-(pyridin-2-yl)-1Н-pyrazol-4-yl)ethan-1-one (L), with iron(III) chloride affords the mononuclear iron(III) complex FeL₂Cl₃, which is characterized by XRD (CIF file CCDC no. 2309481). The intramolecular hydrogen bond between the protonated pyridyl and acetyl groups in ligand L, which exists in the crystal as a zwitterion, provides the formation of rarely met iron complexes in which the β-diketonate fragment coordinates via the η1 mode. A similar coordination mode along with a possibility of a more favorable η2 coordination provides new possibilities for the design of heteropolynuclear compounds of various structures used in the fabrication of molecular devices of data storage and processing.
- Keywords
- пиразолилпиридины комплексы железа рентгеноструктурный анализ полиядерные комплексы оксо- и нитрофильные ионы
- Date of publication
- 15.07.2024
- Year of publication
- 2024
- Number of purchasers
- 0
- Views
- 11
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