- PII
- 10.31857/S0132344X24080045-1
- DOI
- 10.31857/S0132344X24080045
- Publication type
- Article
- Status
- Published
- Authors
- Volume/ Edition
- Volume 50 / Issue number 8
- Pages
- 502-509
- Abstract
- The first homometal dicubane nickel(II) complex based on unsymmetrically substituted 1,3-diketone (1,1,1-trifluoro-4-(2-methoxyphenyl)butan-2,4-dione) was synthesized and studied by X-ray diffraction using synchrotron radiation (CCDC no. 861889). In the crystal of the complex, nickel atoms are joined into tetrahedra sharing a common vertex with Ni…Ni distances of 3.026–3.127 A; the geometry is completed to a distorted dicubane by μ3-bridging oxygen atoms of the hydroxyl groups. The coordination environment of each metal center is a distorted octahedron, the ligand is deprotonated and performs a bidentate function, forming six-membered chelate rings.
- Keywords
- кубановый комплекс никеля(II) дикетоны комплексообразование
- Date of publication
- 15.08.2024
- Year of publication
- 2024
- Number of purchasers
- 0
- Views
- 12
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