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RAS Chemistry & Material ScienceКоординационная химия Russian Journal of Coordination Chemistry

  • ISSN (Print) 0132-344X
  • ISSN (Online) 3034-5499

3,6-Dipyridyl-1,2,4,5-tetrazine in the Synthesis of Zinc and Cadmium Metal-Organic Frameworks with Anilate-Type Ligands

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PII
10.31857/S0132344X24090023-1
DOI
10.31857/S0132344X24090023
Publication type
Article
Status
Published
Authors
O. Yu. Trofimova
  • Affiliation: Razuvaev Institute of Organometallic Chemistry, Russian Academy of Sciences
Volume/ Edition
Volume 50 / Issue number 9
Pages
544-556
Abstract
New heteroleptic metal-organic frameworks (MOF) of zinc (3D MOF) and cadmium (2D MOF) are prepared by the two-stage synthesis: [Zn(pQ)(DPT)]·2DMF (I) and Cd2(NO3)2-(pQ)(DPT)3]·2DMF·2MeOH (II), where pQ is the 2,5-dihydroxy-3,6-di-tert-butyl-para-benzoquinone dianion, DPT is 3,6-di(pyridin-4-yl)-1,2,4,5-tetrazine, and DMF is N,N-dimethylformamide (DMF). The structures of the compounds are studied by XRD (CIF files CCDC nos. 2332754 (I) and 2332755 (II)). The thermal stability of the MOF is studied by thermogravimetry.
Keywords
анилатный лиганд металл-органические координационные полимеры редокс-активный лиганд рентгеноструктурный анализ термогравиметрический анализ
Date of publication
08.09.2024
Year of publication
2024
Number of purchasers
0
Views
13

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