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RAS Chemistry & Material ScienceКоординационная химия Russian Journal of Coordination Chemistry

  • ISSN (Print) 0132-344X
  • ISSN (Online) 3034-5499

Adducts of Sterically Hindered Tellurium Catecholate with N-Methylpyrrolidone

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PII
10.31857/S0132344X24100033-1
DOI
10.31857/S0132344X24100033
Publication type
Article
Status
Published
Authors
P. A. Petrov
  • Affiliation: Nikolaev Institute of Inorganic Chemistry of the Siberian Branch of the Russian Academy of Sciences
Volume/ Edition
Volume 50 / Issue number 10
Pages
661-668
Abstract
The formation of adducts of tellurium(IV) 3,6-di-tert-butyl catecholate (Te(Cat36)2) with N-methylpyrrolidone (NMP) is studied. The crystallization from a CH2Cl2–NMP–aromatic hydrocarbon mixture is found to result in the formation of dimeric complexes [{Te(Cat36)2}2(μ-NMP)(μ-arene)] (arene = C6H6, C7H8), whereas mononuclear [Te(Cat36)2(NMP)2] is formed from a CH2Cl2–NMP–alkane mixture. The formation of the adducts with aromatic hydrocarbons indicates a possibility of using the tellurium complexes for the separation of hydrocarbon mixtures, including an industrially important benzene–cyclohexane mixture.
Keywords
теллур хиноны рентгеноструктурный анализ N-метилпирролидон ЯМР
Date of publication
15.10.2024
Year of publication
2024
Number of purchasers
0
Views
10

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