- PII
- 10.31857/S0132344X24100059-1
- DOI
- 10.31857/S0132344X24100059
- Publication type
- Article
- Status
- Published
- Authors
- Volume/ Edition
- Volume 50 / Issue number 10
- Pages
- 679-692
- Abstract
- In an attempt to synthesize a new iminomethylphosphine, tBuC(Ph2P)=N-Btd (Btd = 2,1,3-benzothiadiazole) by a three-step procedure including (1) NH2-Btd + tBuC(=O)Cl → tBuC(=O)NH-Btd; (2) tBuC(=O)NH-Btd + SOCl2 → tBuC(Cl)=N-Btd; (3) tBuC(Cl)=N-Btd + Ph2PSiMe3 → tBuC(Ph2P)=N-Btd, it was found that the second step is accompanied by the chlorination of the carbocycle in the benzothiadiazole moiety. The reaction of the imidoyl chloride tBuC(Cl)=N-(7-Cl-Btd) formed in this reaction with Ph2PSiMe3 gave 1,3-iminomethylphosphine tBuC(Ph2P)=N-(7-Cl-Btd) (PC=N). The byproducts formed in this step include 1,3-aminomethylphosphine oxide tBuC{Ph2P(O)}NH-(7-Cl-Btd) (POCN) and (Ph2POx)2,, resulting from partial oxidation and hydrolysis. The reactions of PC=N and POCN with [Pt(COD)Cl2] (COD = 1.3-cyclooctadiene) were studied. In the case of PC=N, the reaction affords the [Pt(PC=N)2Cl2] complex. In the latter case, cleavage of the P–C bond in POCN takes place, and [PtCl2(Ph2POH)2](POCN) and [Pt(CH3CN){tBuC-NH-(7-Cl-Btd)}Cl]. are isolated from the reaction mixture. The structures of the new compounds were established by single-crystal X-ray diffraction (tBuC(Cl)N-(7-Cl-Btd)), 2335152 (POCN · Et2O), 2335149 (Ph2POx)2, 2335153 ([Pt(PC=N)2Cl2]), 2335154 ([PtCl2(Ph2POH)2](POCN)), 2335151 ([Pt(CH3CN)(tBuC-NH-(7-Cl-Вbtd))Cl]).
- Keywords
- минометилфосфин бензотиадиазол комплекс Pt аминометилфосфиноксид
- Date of publication
- 15.10.2024
- Year of publication
- 2024
- Number of purchasers
- 0
- Views
- 8
References
- 1. Bálint E., Tajti Á., Tripolszky A., Keglevich G. // Dalton Trans. 2018. V. 47. P. 4755.
- 2. Smith M.B. // Molecules. 2022. V. 27. P. 6293.
- 3. Sukhikh T.S., Khisamov R.M., Konchenko S.N. // Symmetry. 2023. V. 15. P. 157.
- 4. Khisamov R.M., Sukhikh T.S., Konchenko S.N., Pushkarevsky N.A. // Inorganics. 2022. V. 10. P. 263.
- 5. Khisamov R.M., Ryadun A.A., Konchenko S.N., Sukhikh T.S. // Molecules. 2022. V. 27. P. 8162.
- 6. Baranov A.Y., Sukhikh T.S., Artem′ev A.V. // J. Struct. Chem. 2022. V. 63. P. 658.
- 7. Rogovoy M.I., Bagryanskaya I.Y., Sadykov E.H. // J. Struct. Chem. 2023. V. 64. P. 1654.
- 8. Rong M.K., Holtrop F., Slootweg J.C., Lammertsma K. // Coord. Chem. Rev. 2019. V. 380. P. 1.
- 9. Huber T., Bauer J.O. // Chem. Eur. J. 2023. P. e202303760.
- 10. Farkas G., Császár Z., Tóth-Farsang E. et al. // J. Organomet. Chem. 2023. V. 994. P. 122723.
- 11. Liu R., Liu Y., Yang W., Li X., Feng L. // ACS Omega. 2023. V. 8. P. 18290.
- 12. Reis Conceição N., Mahmoud A.G., Guedes da Silva M.F.C. et al. // Mol. Catal. 2023. V. 549. P. 113512.
- 13. Radcliffe J.E., Batsanov A.S., Smith D.M., Scott J.A. et al. // ACS Catalysis. 2015. V. 5. P. 7095.
- 14. van Dijk T., Burck S., Rong M.K. et al. // Angew. Chem. Int. Ed. 2014. V. 53. P. 9068.
- 15. Rong M.K., van Duin K., van Dijk T. et al. // Organometallics. 2017. V. 36. P. 1079.
- 16. Kandel R., Huynh K., Dalgliesh L. et al. // Inorg. Chim. Acta. 2016. V. 445. P. 117.
- 17. Lee K.-F., Yang T., Tsang L.-Y. et al. // Organometallics. 2021. V. 40. P. 358.
- 18. Kandel R., Schatte G., Jessop P.G. // Dalton Trans. 2019. V. 48. P. 12512.
- 19. Fischer M., Steinert H., Schmidtmann M., Beckhaus R. // Dalton Trans. 2019. V. 48. P. 1936.
- 20. Sheldrick G. // Acta Crystallogr. A. 2015. V. 71. P. 3.
- 21. Sheldrick G. // Acta Crystallogr. 2015. V. 71. P. 3.
- 22. Dolomanov O.V., Bourhis L.J., Gildea R.J. et al. // J. Appl. Crystallogr. 2009. V. 42. P. 339.
- 23. Alexeev A.V., Gromilov S.A. // J. Struct. Chem. 2010. V. 51. P. 156.
- 24. Alexeev A.V., Gromilov S.A. // J. Struct. Chem. 2010. V. 51. P. 744.
- 25. Prescher C., Prakapenka V.B. // High Pressure Res. 2015. V. 35. P. 223.
- 26. Afonin M.Y., Martynenko P.A., Kolybalov D.S. // Inorg. Chem. 2024. V. 63. P. 369.
- 27. Sukhikh T.S., Kolybalov D.S., Khisamov R.M., Konchenko S.N. // J. Struct. Chem. 2022. V. 63. P. 1446.
- 28. Nieger M., Schinkels B., Niecke E. // Experimental Crystal Structure Determination. CCDC 174103. 2002. https://doi.org/10.5517/cc5v57d.
- 29. Dashti-Mommertz A., Neumüller B. // Z. Anorg. Allg. Chem. 1999. V. 625. P. 954.
- 30. Tam E.C.Y., Maynard N.A., Apperley D.C. // Inorg. Chem. 2012. V. 51. P. 9403.
- 31. Khisamov R.M., Konchenko S.N., Sukhikh T.S. // J. Struct. Chem. 2022. V. 63. P. 2113.
- 32. Hu C., Wang M., Han X., Fan J. // J. Phys. Chem. C. 2021. V. 125. P. 22346.
- 33. Khisamov R.M., Ryadun A.A., Konchenko S.N., Sukhikh T.S. // Molecules. 2022. V. 27. P. 3857.
