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RAS Chemistry & Material ScienceКоординационная химия Russian Journal of Coordination Chemistry

  • ISSN (Print) 0132-344X
  • ISSN (Online) 3034-5499

Copper(II) 2-(N-tosylamino)benzaldehyde benzoylhydrazone complexes: synthesis, structures, properties, and biological activity

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PII
10.31857/S0132344X24120026-1
DOI
10.31857/S0132344X24120026
Publication type
Article
Status
Published
Authors
B. V. Chal’tsev
  • Affiliation: Southern Federal University
Volume/ Edition
Volume 50 / Issue number 12
Pages
818-832
Abstract
A number of new copper(II) complexes of 2-(N-tosylamino)benzaldehyde benzoylhydrazone (H2L) CuLLn (n = 1–6) with heterocyclic donor ligands (L1 = 1-propyl-2-aminobenzimidazole, L2 = 1-hexyl-2-aminobenzimidazole, L3 = 1-octyl-2-aminobenzimidazole, L4 = 2,2΄-bipyridine, L5 = 1,10-phenanthroline, and L6 = 2-aminopyridine) is synthesized. The structures and compositions of the synthesized compounds are determined by elemental analysis, 1Н NMR spectroscopy, IR spectroscopy, and magnetochemistry. The molecular structures of complexes CuLL1,2,4–6 are determined by XRD (CIF files CCDC nos. 2341480 (CuLL1), 2341468 (CuLL2), 2341478 (CuLL4), 2341477 (CuLL5), and 2341479 (CuLL6)). The biological activity of the complexes is studied. The adducts with L1, L2, and L6 exhibit a significantly higher anti-protist activity than chloroquine used as the reference compound.
Keywords
бензоилгидразон 2-(N-тозиламино)бензальдегид комплексы меди(II) ИК-спектроскопия рентгеноструктурный анализ биологическая активность
Date of publication
24.12.2024
Year of publication
2024
Number of purchasers
0
Views
10

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