RAS Chemistry & Material ScienceКоординационная химия Russian Journal of Coordination Chemistry

  • ISSN (Print) 0132-344X
  • ISSN (Online) 3034-5499

Structural modifications of the platinum(II) isocyanide complexes changing their solid-state luminescence

PII
10.31857/S0132344X24120068-1
DOI
10.31857/S0132344X24120068
Publication type
Article
Status
Published
Authors
Volume/ Edition
Volume 50 / Issue number 12
Pages
860-868
Abstract
Cyclometallated platinum(II) complexes with the general formula [Pt(Рpy)(CNR)2]X (HРpy = 2-phenylpyridine; R = iPr, tBu, Cy; X = BF4, OTf, PF6) containing various alkylisocyanide ligands and counterions are synthesized. The compounds are studied by elemental analysis, ESI HRMS, IR spectroscopy, and 1H, 13C{1H}, and 195Pt{1H} NMR spectroscopy. The structures of [Pt(Рpy)(CNiPr)2]BF4 and [Pt(Рpy)(CNtBu)2]BF4 are determined by XRD (CIF files CCDC nos. 2325595 and 2325527, respectively). The photophysical properties in the solution and in the solid state of the synthesized compounds are studied.
Keywords
комплексы платины нековалентные взаимодействия люминесценция изоцианидные лиганды
Date of publication
24.12.2024
Year of publication
2024
Number of purchasers
0
Views
14

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