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RAS Chemistry & Material ScienceКоординационная химия Russian Journal of Coordination Chemistry

  • ISSN (Print) 0132-344X
  • ISSN (Online) 3034-5499

1D Polymeric Iodoantimonates(III) with 1-Methylpyridinium and 3-Bromo-1-methylpyridinium Cations: Structures and Properties

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PII
S0132344X25010023-1
DOI
10.31857/S0132344X25010023
Publication type
Article
Status
Published
Authors
N. A. Korobeinikov
  • Affiliation:
    Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences
    Novosibirsk State University
M. V. Kozlova
  • Affiliation:
    Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences
    Favorskii Institute of Chemistry, Siberian Branch, Russian Academy of Sciences
Volume/ Edition
Volume 51 / Issue number 1
Pages
12-19
Abstract
The reactions of SbI3 with iodides of cations of the pyridinium family in a mixture of acetonitrile and acetone afford two polymeric iodoantimonate complexes: (1-MePy)[SbI4] (I) and (3-Br-1-MePy)[SbI4] (II). Specific features of the crystal structures are determined by X-ray diffraction (XRD). The thermal stability of compounds I and II is evaluated by thermogravimetry. The optical forbidden bandgaps are estimated from the diffuse reflectance spectra.
Keywords
рентгеноструктурный анализ комплексные соединения галогенидные комплексы нековалентные взаимодействия сурьма
Date of publication
14.09.2025
Year of publication
2025
Number of purchasers
0
Views
5

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