- PII
- S0132344X25070047-1
- DOI
- 10.31857/S0132344X25070047
- Publication type
- Article
- Status
- Published
- Authors
- Volume/ Edition
- Volume 52 / Issue number 7
- Pages
- 456-463
- Abstract
- The paper studies reactions of iron(II) complexation with benzimidazole derivatives L (L = CNH, L = CNH) in the presence of salts of boron cluster anions [BH] ( = 10, 12). The obtained complex compounds of the general formula [FeL][BH] are characterized by elemental analysis and IR spectroscopy. The structure of complex [FeL][BH] is determined by single-crystal X-ray diffraction (CCDC № 2432134). The distorted octahedral environment of the Fe atom is formed by the imidazole and pyridine N atoms of three L molecules. In the crystal, the [FeL] complex has a meridional configuration. The Fe-N bond lengths for imidazolium nitrogen atoms are in the range of 1.954(8)-1.980(6) Å, and for pyridine nitrogen atoms 1.977(7)-2.011(8) Å.
- Keywords
- кластерные анионы бора комплексообразование рентгеноструктурный анализ
- Date of publication
- 18.05.2025
- Year of publication
- 2025
- Number of purchasers
- 0
- Views
- 2
References
- 1. Greenwood N.N., Earnshaw A. Chemistry of the elements. school of chemistry, Butterworth-Heinemann (U.K.): University of Leeds, 1997.
- 2. Boron science: new technologies and applications / Ed. Hosmane N.S. CRC Press, 2012.
- 3. Boron-based compounds: potential and emerging applications in medicine / Eds. Hey-Hawkins E., Viñas Teixidor C. John Wiley & Sons Ltd., 2018. https://doi.org/10.1002/9781119275602
- 4. Zhizhin K.Y., Zhdanov A.P., Kuznetsov N.T. // Russ. J. Inorg. Chem. 2010. V. 55. № 14. P. 2089. https://doi.org/10.1134/S0036023610140019
- 5. Sivaev I.B., Prikaznov A.V., Naoufal D. // Collect. Czech. Chem. Commun. 2010. V. 75. P. 1149. https://doi.org/10.1135/cccc2010054
- 6. Mahfouz N., Abi Ghaida F., El Hajj F. et al. // ChemistrySelect. 2022. V. 7. Art. e202200770. https://doi.org/10.1002/slct.202200770
- 7. Matveev E.Y., Avdeeva V.V., Zhizhin K.Yu. et al. // Inorganics. 2022. V. 10. P. 238. https://doi.org/10.3390/inorganics10120238
- 8. Zhang Y., Cai Z., Chen Z. et al. // Chin. J. Struct. Chem. 1982. V. 1. P. 46.
- 9. Zhang Y., Chen Z., Cai Z. et al. // Chin. J. Struct. Chem. 1982. V. 2. P. 201.
- 10. Avdeeva V.V., Vologzhanina A.V., Goeva L.V. еt al. // Z. Anorg. Allg. Chem. 2014. V. 640. № 11. P. 2149. https://doi.org/10.1002/zaac.201400137
- 11. Короленко С.Е., Авдеева В.В., Малинина Е.А. и др. // Коорд. химия. 2020. Т. 46. № 5. С. 259
- 12. Korolenko S.E., Avdeeva V.V., Malinina E. A. et al. // Russ. J. Coord. Chem. 2020. V. 45. No. 5. P. 297. https://doi.org/10.1134/S1070328420050024
- 13. Nguyen Duc Van. Thesis: New salt-like dodecahydro-closo-dodecaborates and efforts for the partial hydroxylation of [B12H12]2- anions. Stuttgart: Institut fűr Anorganische Chemie der Universitat, 2009.
- 14. Avdeeva V.V., Kubasov A.S., Korolenko S.E. et al. // Polyhedron. 2022. V. 217. P. 115740. https://doi.org/10.1016/j.poly.2022.115740
- 15. Sirivardane U., Chu S.S.C., Hosmane N.S. et al. // Acta Crystallogr. 1989. p. 333. https://doi.org/10.1107/S0108270188010716
- 16. Nikiforova S.E., Kubasov A.S., Son A.G. et al. // Inorg. Chim. Acta. 2023. V. 557. P. 121654. https://doi.org/10.1016/j.ica.2023.121654
- 17. Ivanova A.D., Lavrenova L.G., Korotaev E.V. et al. // Russ. J. Inorg. Chem. 2020. V. 65. P. 1687. https://doi.org/10.1134/S0036023620110078
- 18. Lavrenova L.G., Dyukova I.I., Korotaev E.V. et al. // Russ. J. Inorg. Chem. 2020. V. 65. P. 30. https://doi.org/10.1134/S0036023620010106
- 19. Ivanova A.D., Lavrenova L.G., Korotaev E.V. et al. // Russ. J. Inorg. Chem. 2022. V. 67. P. 1158. https://doi.org/10.1134/S0036023622080174
- 20. Lavrenova L.G., Shakirova O.G. // Russ. J. Inorg. Chem. 2023. V. 68. P. 690. https://doi.org/10.1134/S0036023623600764
- 21. Kravchenko E.A., Gippius A.A., Polyakova I.N. et al. // ZAAC. 2017. V. 643. P. 1939. https://doi.org/10.1002/zaac.201700293
- 22. Voloshin Y.Z., Varzatskii O.A., Zhizhin K.Y. et al. // Russ. Chem. Bull. 2006. V. 55. P. 22. https://doi.org/10.1007/s11172-006-0210-6
- 23. Авдеева В.В., Вологжанина А.В., Гоева Л.В. и др. // Докл. РАН. 2015. Т. 461. № 6. С. 664
- 24. Avdeeva V.V., Vologzhanina A.V., Goeva L.V. et al. // Dokl. Chem. 2015. V. 461 P. 96. https://doi.org/10.1134/S0012500815040035
- 25. Авдеева В.В., Полякова И.Н., Гоева Л.В. и др. // Журн. неорган. химии. 2015. Т. 60. № 7. С. 9019
- 26. Avdeeva V.V., Polyakova I.N., Goeva L.V. et al. // Russ. J. Inorg. Chem. 2015. V. 60. P. 817. https://doi.org/10.1134/S0036023615070037
- 27. Miller H.C., Miller N.E., Muetterties E.L. // J. Am. Chem. Soc. 1963. V.85. P. 3885. https://doi.org/10.1021/ja00906a033
- 28. Greenwood N.N., Morris J.H. // Proc. Chem. Soc. 1963. № 11. P. 338.
- 29. Бурлов А.С., Анцышкина А.С., Садиков Г.Г. и др. // Коорд. химия. 2010. Т. 36. № 12. С. 918 (Russ. J. Coord. Chem. 2010. V. 36. № 12. P. 906). https://doi.org/10.1134/S1070328410120079
- 30. SAINT. Madison (WI, USA): Bruker AXS Inc., 2018.
- 31. Krause L., Herbst-Irmer R., Sheldrick G.M., Stalke D.J. // Appl. Crystallogr. 2015. V. 48. № 1. P. 3. https://doi.org/10.1107/S1600576714022985
- 32. Sheldrick G.M. // Acta Crystallogr. C. 2015. V. 71. P. 3. https://doi.org/10.1107/S2053229614024218
- 33. Dolomanov O.V., Bourhis L.J., Gildea R.J. et al. // J. Appl. Cryst. 2009. V. 42. P. 339. https://doi.org/10.1107/S0021889808042726
- 34. Spackman P.R., Turner M.J., McKinnon J.J. et al. // J. Appl. Crystallogr. 2021. V. 54. P. 1006. https://doi.org/10.1107/S1600576721002910
- 35. Keikha M., Pourayoubi M., Tarahhomi A. et al. // Z. Krist. Mater. 2017. V. 232. № 6. P. 453.
- 36. Spackman M.A., Jayatilaka D. // CrystEngComm. 2009. V. 11. № 1. P. 19.
