- PII
- S3034549925040059-1
- DOI
- 10.7868/S3034549925040059
- Publication type
- Article
- Status
- Published
- Authors
- Volume/ Edition
- Volume 51 / Issue number 4
- Pages
- 255-264
- Abstract
- Single crystals of the Mn(III) complexes with tetradentate (N2O2) Schiff bases (L) and dicyanometallates [Mn(L)M(CN)2]n, where L = Salpn2– = N,N’-bis(salicylidene)-1,3-diaminopropane, M = M = Ag+ (I), Au+ (II) were obtained for the first time. The molecular structures of I and II were determined by X-ray diffraction (CCDC no. 2351118 (I), 2351119 (II)). It was found that the dicyanometallate anion [M(CN)2]ˉ in the crystal structure of these compounds acts as a bridge binding the Mn(III) moieties with the Schiff base into 1D. Using quantum chemical calculations, the (3, –1) type critical points were found near the C‒H…Ag/Au contact; this attests to the existence of weak hydrogen bonds between these atoms.
- Keywords
- комплексы марганца (III) основание Шиффа дицианометаллаты рентгеноструктурный анализ квантово-химических расчеты
- Date of publication
- 15.04.2025
- Year of publication
- 2025
- Number of purchasers
- 0
- Views
- 84
References
- 1. Сапьяник А.А., Федин В.П. // Коорд. химия. 2020. Т. 46. № 7. С. 387.
- 2. Lawrance G.A. Encyclopedia of Inorganic Chemistry. John Wiley & Sons, Ltd., 2006. 22 p.
- 3. Miyasaka H., Saitoh A., Abe S. // Coord. Chem. Rev. 2007. V. 251. P. 2622.
- 4. Oki A.R., Hodgson D.J. // Inorg. Chim. Acta. 1990. V. 170. № 1. P. 65.
- 5. Miyasaka H., Matsumoto N., Okawa H. et al. // Angew. Chem. Int. Ed. 1995. V. 34. P. 1446.
- 6. Re N., Gallo E., Floriani C. et al. // Inorg. Chem. 1996. V. 35. P. 6004
- 7. Sakamoto F., Sumiya T., Fujita M. et al. // Chem. Lett. 1998. V. 27. P. 1127.
- 8. Miyasaka H., Clerac R., Ishii T. et al. // Dalton Trans. 2002. № 7. P. 1528.
- 9. Paraschiv C., Andruh M., Ferlay S. et al. // Dalton Trans. 2005. № 7. P. 1195.
- 10. Niel V., Thompson A.L., Munoz M.C. et al. // Angew. Chem. Int. Ed. 2003. V. 42. P. 3760.
- 11. Shorrock C.J., Xue B.Y., Kim P.B. // Inorg. Chem. 2002. V. 41. P. 6743.
- 12. Leznoff D.B., Xue B.Y., Batchelor R.J. // Inorg. Chem. 2001. V. 40. P. 6026.
- 13. Leznoff D.B., Xue B.Y., Stevens C.L. et al. // Polyhedron. 2001. V. 20. P. 1247.
- 14. Dong W., Zhu L.N., Sun Y.Q. et al. // Chem. Commun. 2003. № 20. P. 2544.
- 15. Ashmawy F.M., McAuliffe C.A., Parish R.V., Tames J. // Dalton Trans. 1985. № 7. P. 1391.
- 16. Fujisawa K., Nemoto T., Morishima Y. et al. // Molecules. 2021. V. 26. № 4. P. 1015;
- 17. Накамото К. Инфракрасные спектры неорганических и координационных соединений. M.: Мир, 1966. 411 с.
- 18. Sheldrick G.M. SADABS. Gőttingen (Germany): Univ. of Gőttingen, 1996.
- 19. Sheldrick G.M. // Acta Crystallogr. A. 2008. V. 64. P. 112.
- 20. Sheldrick G.M. // Acta Crystallogr. C. 2015. V. 71. P. 3.
- 21. Frisch M.J., Trucks G.W., Schlegel H.B. et al. Gaussian 09., Revision C.01. Wallingford (CT): Gaussian, Inc., 2009.
- 22. Koskinen L., Jääskelдinen S., Kalenius E. et al. // Cryst. Growth. Des. 2014. V. 14. P. 1989.
- 23. Schmidbaur H., Raubenheimer H.G., Dobrzaсska L. // Chem. Soc. Rev. 2014. V. 43. P. 345.
- 24. Andris E., Straka M., Vrána J. et al. // Chem. Eur. J. 2023. V. 29. P. e202203769.
- 25. Keith T.A. AIMAll. TK Gristmill Software. Version 15.05.18. Overland Park, KS, USA, 2015. aim.tkgristmill.com
- 26. Clark T., Murray J., Politzer P. // Phys. Chem. Chem. Phys. 2018. V. 20. P. 30076.
- 27. Miyasaka H., Clerac R., Wernsdorfer W. et al. // Angew. Chem. Int. Ed. Eng. 2004. V. 43 № 21. P 2801.
- 28. Feng Y., Guo Y., OuYang Y. et al. // Chem. Commun. 2007. № 35. P. 3643.
- 29. Lusi M., Barbour L.J. // Cryst. Growth. Des. 2011. V. 11. P. 5515;
- 30. Wang X.-B., Wang Y.-L., Yang J. et al. // J. Am. Chem. Soc. 2009. V. 131. P. 16368.
- 31. Nastase S., Maxim C., Duhayon C. et al. // Rev. Roum. Chim. 2013. V. 58. P. 355.
- 32. Ababei R., Li Y.-G., Roubeau O. et al. // New J. Chem. 2009. V. 33. P. 1237.
- 33. Si S.-F., Tang J.-K., Liu Z.-Q. et al. // Inorg. Chem. Commun. 2003. V. 6. P. 1109.
- 34. Kopotkov V.A., Sasnovskaya V.D., Korchagin D.V. et al. // CrystEngComm 2015. V. 17. P. 3866.
- 35. Kopotkov V.A., Yagubskii E.B., Simonov S.V. et al. // New J. Chem. 2014. V. 38. P. 4167.
