Везде

RAS Chemistry & Material ScienceКоординационная химия Russian Journal of Coordination Chemistry

  • ISSN (Print) 0132-344X
  • ISSN (Online) 3034-5499

Terephthalate and N-Oxide Isonicotinate Complexes of the {MoI} Cluster

You can
PII
S30345499S0132344X25090025-1
DOI
10.7868/S3034549925090025
Publication type
Article
Status
Published
Authors
M. A. Mikhaylov
  • Affiliation: Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences
T.S. Sukhikh
  • Affiliation: Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences
D.G. Sheven
  • Affiliation: Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences
E.H. Sadykov
  • Affiliation: Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences
M.N. Sokolov
  • Affiliation:
    Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences
    Novosibirsk National Research State University
A.S. Berezin
  • Affiliation: Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences
K.A. Tagil'tsev
  • Affiliation: Novosibirsk National Research State University
Volume/ Edition
Volume 51 / Issue number 9
Pages
556-565
Abstract
The reaction of (TBA)[MoI(OAc)] with terephthalic acid and isonicotinic acid N-oxide afforded new complexes, (TBA)[MoI(ООС–CH–COOH)](I) and (TBA)[MoI(ООС– CHNO)] (II), respectively. The optimized synthesis of complex II involves microwave activation of the reaction mixture at 130°C in a Teflon reactor of the ETHOS UP Milestone microwave setup. According to X-ray diffraction data, the molybdenum atoms in the cluster cores of I and II are monodentately coordinated by carboxylate ligands. The cluster anions of complex I [MoI(ООС–CH–COOH)] are combined into a three-dimensional structure, the crystal structure contains solvate molecules. Samples of complexes I and II were characterized by elemental analysis for C, H, N, IR spectroscopy, electrospray mass spectrometry and proton magnetic resonance. For powder samples of I and II, bright phosphorescence with emission maxima at ~680 nm, φ = 15%, τ = 125 μs (I) and φ = 12%, τ = 137 μs (II) (in air at λ = 440 nm) was revealed.
Keywords
кластеры иодид молибдена (II) карбоксилатные комплексы рентгеноструктурный анализ ядерный магнитный резонанс микроволновая активация
Date of publication
15.09.2025
Year of publication
2025
Number of purchasers
0
Views
37

References

  1. 1. Gassan A.D., Ivanov A.A., Pozmogova T.N. et al. // Int. J. Mol. Sci. 2022. V. 23. P. 8734.
  2. 2. Pozmogova T.N., Sitnikova N.A., Pronina E.V. et al. // Mater. Chem. Front. 2021. V. 5. P. 7499.
  3. 3. Ivanov A.A., Haouas M., Evtushok D.V., Pozmogova T.N. et al. // Inorg. Chem. 2022. V. 61. P. 14462.
  4. 4. Neaime C., Amela-Cortes M., Grasset F., Molard Y. et al. // Phys. Chem. Chem. Phys. 2016. V. 18. P. 30166.
  5. 5. Muxatiaoa M.A., Coscao M.H. // Изв. AH. Сер. хим. 2024. Т. 73(6), С. 1541.
  6. 6. Kirakci K., Zelenka J., Rumlová M. et al. // Biomater. Sci. 2019. V. 7. P. 1386.
  7. 7. Felip-Leon C., del Valle C.A., Perez-Laguna V. et al. // J. Mater Chem. B. 2017. V. 5. P. 6058.
  8. 8. Vorotnikova N.A., Bardin V.A., Vorotnikov Y.A. et al. // Dalton Trans. 2021. V. 50. P. 8467.
  9. 9. Vorotnikova N.A., Alekseev A.Y., Vorotnikov Y.A. et al. // Mater. Sci. Engineering. 2019. V. 105. P. 110.
  10. 10. Ivanova M.N., Vorotnikov Y.A., Plotnikova E.E. et al. // Inorg. Chem. 2020. V. 59. P. 6439.
  11. 11. Petunin A.A., Evtushok D.V., Vorotnikova N.A. et al. // Eur. J. Inorg. Chem. 2020. V. 2020. P. 2177.
  12. 12. Felix M., Atienza P., Amela-Cortes M. et al. // Inorg. Chem. 2019. V. 58. P. 15443.
  13. 13. Beltran A., Mikhailov M., Sokolov M.N. et al. // J. Mater. Chem. B. 2016. V. 4. P. 5975.
  14. 14. Puche M., Garcia-Aboal R., Mikhaylov M.A. et al. // Nanomaterials. 2020. V. 10. P. 1259.
  15. 15. Nguyen T.K.N., Grasset F., Cordier S. et al. // Adv. Powder Technol. 2020. V. 31. P. 895.
  16. 16. Amela-Cortes M., Paofai S., Cordier S. et al. // Chem. Commun. 2015. V. 51. P. 8177.
  17. 17. Ghosh R.N., Baker G.L., Ruud C., Nocera D.G. et al. // Appl. Phys. Lett. 1999. V. 75. P. 2885.
  18. 18. Prevot M., Amela-Cortes M., Manna S.K. et al. // Adv. Funct. Mater. 2015. V. 25. P. 4966.
  19. 19. Molina E.F., Martins de Jesus N.A., Paofai S. et al. // Chem. Eur. J. 2019. V. 25. P. 1.
  20. 20. Robin M., Dumait N., Amela-Cortes M. et al. // Chem. Eur. J. 2018. V. 24. P. 4825.
  21. 21. Effemova O.A., Brylev K.A., Vorotnikov Y.A. et al. // J. Mater. Chem. C. 2016. V. 4. P. 497.
  22. 22. Kinakci K., Sicho V., Holub J. et al. // Inorg. Chem. 2014. V. 53. P. 13012.
  23. 23. Aubert T., Cabello-Hurtado F., Esnault M.A. et al. // J. Phys. Chem. C. 2013. V. 117. P. 20154.
  24. 24. Truong T.G., Dierre B., Grasset F. et al. // Sci. Technol. Adv. Mater. 2016. V. 17. P. 443.
  25. 25. Mikhavlov M.A., Abramov P.A., Komarov V.Y., Sokolov M.N. // Polyhedron 2017. V. 122. P. 241.
  26. 26. Vorotnikov Y.A., Effemova O.A., Vorotnikova N.A. et al. // RSC Adv. 2016. V. 6. P. 43367.
  27. 27. Evushok D.V., Melnikov A.R., Vorotnikova N.A. et al. // Dalton Trans. 2017. V. 46. P. 11738.
  28. 28. Sverhentseva E.V., Vorotnikov Y.A., Solovieva A.O. et al. // Chem. Eur. J. 2018. V. 24. P. 17915.
  29. 29. Mikhailov M.A., Brylev K.A., Abramov P.A. et al. // Inorg. Chem. 2016. V. 55. P. 8437.
  30. 30. Akagi S., Fujii S., Horiguchi T., Kitamura N. // J. Cluster Sci. 2017. V. 28. P. 757.
  31. 31. Muzalizoe M.A., Bepezun A.C., Cyxux T.C. u dp. // XCX. 2021. T. 62. C. 1896.
  32. 32. Mironova A.D., Mikhavlov M.A., Maksimov A.M. et al. // Eur. J. Inorg. Chem. 2022. V. 2022. P. e202100890(1–11).
  33. 33. Sokolov M.N., Brylev K.A., Abramov P.A. et al. // Eur. J. Inorg. Chem. 2017. V. 2017. P. 4131.
  34. 34. Muzalizoe M.A., Afpavoe H.A., Muponosa A.J., u dp. // Koopn. химия. 2019. T. 45. C. 58 (Mikhailov M.A., Abramov P.A., Mironova A.D. et al. // Russ. J. Coord. Chem. 2019. V. 45. P. 56). https://doi.org/10.1134/S1070328419010081
  35. 35. Bozoennikov M.B., Лобода П.А., Синельщикова А.А., u dp. // Журн. неорган. химии. 2023. T. 68. № 9. С. 1192–1201.
  36. 36. Volostnykh M.V., Mikhaylov M.A., Sinelshchikova A.A. et al. // Dalton Trans. 2019. V. 48. № 5. P. 1835.
  37. 37. Volostnykh M.V., Kirakosyan G.A., Sinelshchikova A.A. et al. // Dalton Trans. 2023. V. 52. № 16. P. 5354.
  38. 38. Sheldrick G. // Acta Crystallogr. Sect. A. 2015. V. 71. P. 3. DOI: 10.1107/S2053273314026370
  39. 39. Sheldrick G. // Acta Crystallogr. Sect. C. 2015. V. 71. P. 3–8. DOI: 10.1107/S2053229614024218.
  40. 40. Dolomarov, O.V., Bourhis L.J., Gildea R.J. et al. // J. Appl. Crystallogr. 2009. V. 42. P. 339. DOI: 10.1107/S002188980842726.
  41. 41. Lide D.R. // CRC Handbook of Chemistry and Physics; CRC Press: Boca Raton, FL, 2009.
  42. 42. Chongqing Chenndad Co. Ltd. https://www.chenndad.com/
  43. 43. Bernstein J., Davis R.E., Shimoni L., Chang N.-L. // Angew. Chem. Int. Ed. Engl. 1995. 34. P. 1555.
  44. 44. Muzalizoe M.A., Bepezun A.C., Cyxux T.C. u dp. // Журн. структ. химии. 2022. T. 63. 103869.
  45. 45. Nosov V.G., Toikka Y.N., Petrova A.S. et al. // Molecules. 2023. V. 28(5). P. 2378.
  46. 46. Nosov V.G., Kupryakov A.S., Kolesnikov I.E. et al. // Molecules. 2022. V. 27(18). P. 5763.
  47. 47. Butorlin O.S., Petrova A.S., Toikka Y.N. et al. // Molecules. 2024. 29(15). P. 3558.
  48. 48. Miao Du, Cheng-Peng Li, Jian-Hua Guo // CrystEngComm. 2009. V. 11. P. 1536.
  49. 49. Stefan L., Zbigniew G., Guenther M., Maciej K. // J. Chem. Crystallogr. 2010. V. 40. P. 646.
QR
Translate

Индексирование

Scopus

Scopus

Scopus

Crossref

Scopus

Higher Attestation Commission

At the Ministry of Education and Science of the Russian Federation

Scopus

Scientific Electronic Library