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RAS Chemistry & Material ScienceКоординационная химия Russian Journal of Coordination Chemistry

  • ISSN (Print) 0132-344X
  • ISSN (Online) 3034-5499

Local Atomic Structure of Co(II), Ni(II), and Cu(II) Metallochelates Based on Derivatives of 1-Phenyl-3-Methyl-4-Formyl-5-Pyrazolone and 1-Aminobenzimidazoles

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PII
S30345499S0132344X25090042-1
DOI
10.7868/S3034549925090042
Publication type
Article
Status
Published
Authors
A. A. Shiryaeva
  • Affiliation: Southern Federal University, Scientific Research Institute of Physics
V.G. Vlasenko
  • Affiliation: Southern Federal University, Scientific Research Institute of Physics
A.S. Burlov
  • Affiliation: Southern Federal University, Scientific Research Institute of Physical and Organic Chemistry
T.A. Kuzmenko
  • Affiliation: Southern Federal University, Scientific Research Institute of Physical and Organic Chemistry
V.V. Chesnokov
  • Affiliation: Southern Federal University, Scientific Research Institute of Physical and Organic Chemistry
A.I. Uraev
  • Affiliation: Southern Federal University, Scientific Research Institute of Physical and Organic Chemistry
A.L. Trigub
  • Affiliation: National Research Center "Kurchatov Institute"
Volume/ Edition
Volume 51 / Issue number 9
Pages
576-589
Abstract
A series of new metallochelates of Co(II), Ni(II) and Cu(II) based on 1-phenyl-3-methyl-4-formyl-5-pyrazolone and derivatives of 1-aminobenzimidazoles has been obtained. The composition and spectral properties of which were studied using elemental analysis methods, 1H NMR (for HL) and IR spectroscopy. The parameters of the local atomic environment of metal ions in these complex compounds have been determined by X-ray absorption spectroscopy. The experimental structural data are confirmed by the calculation of optimized structures of complexes using the density functional theory method. The important role of additional donor centers (S, Se) and substituents at the imine nitrogen atom in the aminobenzimidazole fragment of ligands on the geometry of the coordination node of complexes is shown.
Keywords
XANES EXAFS ИК квантово-химические расчеты
Date of publication
15.09.2025
Year of publication
2025
Number of purchasers
0
Views
37

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